@article{Li:2024:10.1021/jacs.4c02220,
author = {Li, B and Gao, D and Sheppard, SA and Tremlett, WDJ and Liu, Q and Li, Z and White, AJP and Brown, RK and Sun, X and Gong, J and Li, S and Zhang, S and Wu, X and Zhao, D and Zhang, C and Wang, Y and Zeng, XC and Zhu, Z and Long, NJ},
doi = {10.1021/jacs.4c02220},
journal = {J Am Chem Soc},
pages = {13391--13398},
title = {Highly Efficient and Scalable p-i-n Perovskite Solar Cells Enabled by Poly-metallocene Interfaces.},
url = {http://dx.doi.org/10.1021/jacs.4c02220},
volume = {146},
year = {2024}
}

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TY  - JOUR
AB  - Inverted p-i-n perovskite solar cells (PSCs) are easy to process but need improved interface characteristics with reduced energy loss to prevent efficiency drops when increasing the active photovoltaic area. Here, we report a series of poly ferrocenyl molecules that can modulate the perovskite surface enabling the construction of small- and large-area PSCs. We found that the perovskite-ferrocenyl interaction forms a hybrid complex with enhanced surface coordination strength and activated electronic states, leading to lower interfacial nonradiative recombination and charge transport resistance losses. The resulting PSCs achieve an enhanced efficiency of up to 26.08% for small-area devices and 24.51% for large-area devices (1.0208 cm2). Moreover, the large-area PSCs maintain >92% of the initial efficiency after 2000 h of continuous operation at the maximum power point under 1-sun illumination and 65 °C.
AU  - Li,B
AU  - Gao,D
AU  - Sheppard,SA
AU  - Tremlett,WDJ
AU  - Liu,Q
AU  - Li,Z
AU  - White,AJP
AU  - Brown,RK
AU  - Sun,X
AU  - Gong,J
AU  - Li,S
AU  - Zhang,S
AU  - Wu,X
AU  - Zhao,D
AU  - Zhang,C
AU  - Wang,Y
AU  - Zeng,XC
AU  - Zhu,Z
AU  - Long,NJ
DO  - 10.1021/jacs.4c02220
EP  - 13398
PY  - 2024///
SP  - 13391
TI  - Highly Efficient and Scalable p-i-n Perovskite Solar Cells Enabled by Poly-metallocene Interfaces.
T2  - J Am Chem Soc
UR  - http://dx.doi.org/10.1021/jacs.4c02220
UR  - https://www.ncbi.nlm.nih.gov/pubmed/38691098
VL  - 146
ER  - 

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