Imperial College London
Professor Henry S. Rzepa

Professor Henry S. Rzepa

Faculty of Natural Sciences, Department of Chemistry

Emeritus Professor of Computational Chemistry
 
 
 
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Contact

 

+44 (0)7514 623 653h.rzepa Website

 
 
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Location

 

501AMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Sebest:2020:10.1002/adsc.201901614,
author = {Sebest, F and Lachhani, K and Pimpasri, C and Casarrubios, L and White, A and Rzepa, H and Díez-González, S},
doi = {10.1002/adsc.201901614},
journal = {Advanced Synthesis & Catalysis},
pages = {1877--1886},
title = {Cycloaddition reactions of azides and electron-deficient alkenes in deep eutectic solvents: pyrazolines, aziridines and other surprises},
url = {http://dx.doi.org/10.1002/adsc.201901614},
volume = {362},
year = {2020}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - The reaction of organic azides and electrondeficient alkenes was investigated in a deep eutectic solvent. A series of highly substituted 2pyrazolines was successfully isolated and their formation rationalised by DFT calculations. The critical effect of substitution was also explored; even relatively small changes in the cycloaddition partners led to completely different reaction outcomes and triazolines, triazoles or enaminones can be formed as major products depending on the alkene employed.
AU  - Sebest,F
AU  - Lachhani,K
AU  - Pimpasri,C
AU  - Casarrubios,L
AU  - White,A
AU  - Rzepa,H
AU  - Díez-González,S
DO  - 10.1002/adsc.201901614
EP  - 1886
PY  - 2020///
SN  - 1615-4150
SP  - 1877
TI  - Cycloaddition reactions of azides and electron-deficient alkenes in deep eutectic solvents: pyrazolines, aziridines and other surprises
T2  - Advanced Synthesis & Catalysis
UR  - http://dx.doi.org/10.1002/adsc.201901614
UR  - https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201901614
UR  - http://hdl.handle.net/10044/1/77397
VL  - 362
ER  -
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